Jaan Laane 텍사스 A&M

Jaan Laane

Department of Chemistry
Texas A&M University
College Station, TX 77842
Phone: (979) 845-3352
Fax: (979) 845-3154
laane@mail.chem.tamu.edu

Professor

Ph. D., Massachusetts Institute of Technology
Editor, Journal of Molecular Structure

Areas of Interest:
Vibrational Spectroscopy and Molecular Structure

진동 분광법과 분자 구조 연구

한양대 안산캠퍼스의 주재범 교수님 지도교수

Laane Research Laboratory

Research efforts on a variety of projects concentrate on the use of fluorescence spectroscopy of jet-cooled molecules and Fourier transform infrared (FT-IR) and laser Raman spectroscopies. Computer methods for quantum mechanical calculations and on-line instrument control are also utilized and developed.

The dynamics of conformational energy changes in electronic ground and excited states are investigated by analyzing the far-infrared, mid-infrared, Raman and fluorescence data using quantum mechanical computational techniques. Such investigations on molecules, which possess large-amplitude motions such as ring inversions or internal rotations, lead to the determination of the equilibrium structures, potential energy barriers, pathways of interconversion and intramolecular forces. Recent work has focused on molecules that require two vibrational coordinates to define their conformations. For example, the conformational changes of cyclopentanes and cyclohexenes containing heteroatoms can be investigated using far-infrared and Raman spectra along with two-dimensional potential energy calculations.

A tunable Nd:YAG based OPO laser system is used to study the conformations of molecules in electronic excited states. A supersonic jet system cools the molecules so that vibrational excited states are thermally depopulated. Fluorescence excitation spectra and ultraviolet absorption spectra, such as those shown below for 1,3-benzodioxole, can be recorded and analyzed to determine the vibrational potential energy surfaces for the electronic excited states of interest. The ultraviolet absorption spectra also shown below nicely complement the fluorescence studies. Dispersed fluorescence spectra aid in the analyses of the ground states. This type of information helps to better understand molecular properties and photochemical pathways in electronic excited states.